Import DXF with arcs from OpenSCAD, FreeCAD or LibreCAD into KiCAD

no, it is a kicad import dxf limit, that can be found at the manual
http://docs.kicad.org/4.0.5/en/pcbnew.html#_creating_a_board

6.1.2. Using a DXF drawing for the board outline
As a first step, any POLYLINES need to be split (Exploded) into their original simpler shapes. In LibreCAD use the following steps:

  • Open a copy of the DXF file.
  • Select the board shape (selected shapes are shown with dashed lines).
  • In the Modify menu, select Explode.
  • Press ENTER.

From your FC setting menu you have Max Spline segment to 5mm…
Move this setting to 0.01mm as suggested by @Joan_Sparky to be able to export correctly also complex spline (which is not your case atm).

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