KiCad does the simulation in the background via ngspice. So it is in general good, to get a grasp of spice type simulations in general (there are various spice simulators which work very similar, for example pspice, ltspice and ngspice) and ngspice in particular.
I would recommend maybe looking at some videos on Youtube. For example Eric Bredder has some very nice (and basic) introduction videos, into how to do simulation with Kicad:
Note: These videos were made with KiCad 5, but the simulation is very similar in KiCad 6, so the videos should still give you a good start, even if you use KiCad 6.
They certainly helped me when I started with this.