Which is the Option to fixed PCB Edge cut board size(100*100)

This question is so basic that it looks like you haven’t gone through any tutorial. Unfortunately the “official” Getting Started with KiCad tutorial is a bit outdated with respect to v5.1. Rene has written a more up-to-date tutorial in Tutorial: Introduction to PCB design with KiCad version 5.1 (Getting Started). Go through it and many of your questions will be answered.

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